Incoloy® Alloy 925, Nickel-Iron-Chromium Superalloy
INCOLOY® alloy 925 (UNS
N09925) is an agehardenable nickel-iron-chromium alloy with additions of
molybdenum, copper, titanium and aluminum. The alloy’s chemical composition, is
designed to provide a combination of high strength and excellent corrosion
resistance. The nickel content is sufficient for protection against chloride-ion
stresscorrosion cracking. The nickel, in conjunction with the molybdenum and copper,
also gives outstanding resistance to reducing chemicals. The molybdenum aids
resistance to pitting and crevice corrosion. The alloy’s chromium content provides
resistance to oxidizing environments. The titanium and aluminum additions cause a
strengthening reaction during heat treatment.
INCOLOY alloy 925 is used in various applications requiring a
combination of high strength and corrosion resistance. Because of the alloy’s
resistance to sulfide stress cracking and stress-corrosion cracking in “sour” (H2S
containing) crude oil and natural gas, it is used for down-hole and surface gaswell
components including tubular products, valves, hangers, landing nipples, tool joints
and packers. The alloy is also useful for fasteners, marine and pump shafting and
high-strength piping systems.
At TorqBolt we stock a huge variety of Studs, Heavy Hex Nuts, washers and
headed bolts along with their corresponding forgings, pipe fittings, flanges, pipes,
plates, sheets and bar stock, wire, wirelines, welding wire and covered electrodes.
| UNS |
N09925 |
| WerkStoff |
2.4858 |
| JIS |
NCF 925 |
| Category |
Description |
Typical Applications for Incoloy 925 |
| Plates and Sheets |
Flat rolled products used for fabrication, machining, or cladding. |
Pressure vessels, heat exchangers, chemical plant linings. |
| Forged Flanges, Fittings, Rings, Forged Pipes |
Components produced by forging for superior mechanical integrity. |
High-pressure flanges, connectors, downhole oilfield tools. |
| Bars and Shapes |
Solid long products, round/square/hex bars, or custom extruded profiles. |
Shafts, fasteners, pump shafts, and machined parts. |
| Fasteners, Stud Bolts, Heavy Hex Nuts |
Precision-machined threaded fasteners for corrosive and high-stress
environments. |
Offshore equipment, chemical process units, sour gas wells. |
| HIP Flanges and Fittings |
Hot-Isostatically-Pressed components with uniform density and strength. |
Subsea and petrochemical equipment needing defect-free materials. |
| Forgings |
Shaped metal components produced via hot or cold deformation. |
Valves, couplings, and mechanical connectors. |
| Pipes, Tubes and Tubings |
Seamless or welded hollow sections used for fluid transport. |
Oil & gas production tubing, flowlines, marine service. |
| Pipe Fittings |
Connectors and joints (elbows, tees, reducers, etc.) for pipe systems. |
Chemical and offshore pipeline installations. |
| Castings |
Components shaped by molten metal pouring, useful for complex geometries.
|
Valve bodies, pump casings, compressor components. |
Incoloy 925 is highly resistant to corrosion in a wide range of
organic and inorganic acids. The copper content gives excellent resistance to corrosion
in many oxidising acids. Commercial acid applications often contain chlorides and other
impurities which can cause corrosion of some stainless steels. Incoloy 925 offers much
improved corrosion performance in these environments.
Figure 2 : Iso-corrosion curves 0.004 ipy (0.1mm/y)
for some stainless
steels in Sulfuric Acid
Figure 3 : Iso-corrosion curves 0.004 ipy (0.1mm/y)
for some stainless
steels in Hydrochloric Acid
Incoloy 925 is also highly resistant to strong alkalis. The
production of caustic soda results in hot, strong solutions and even in 60 wt% caustic
soda, Incoloy 925 has very low corrosion rates (<0.004 ipy). Caustic soda is often
found with chlorides in extraction processes and even with 10g/L chloride, Incoloy 925
has excellent corrosion resistance. Three years service experience of fabricated
Incoloy 925 pipework in 2M caustic soda with chlorides at 446°F (230°C) has been
excellent.
Exposure to 6% FeCl3 for 24 hours in accordance with ASTM G48
method A to determine the maximum temperature at which no pitting occurs (the critical
pitting temperature, CPT), has given the following results:
Solution annealed wrought and cast Incoloy 925: 158 - 176°F (70-80°C) depending on
product form and manufacturing route.
Incoloy 925 welded with Zeron 100X filler
metal: 95-140°F (35 - 60°C), depending on the welding variables, i.e. process, joint
geometry, procedure etc.
These values are for single exposure testing; testing a
single specimen at a series of increasing temperatures gives a higher CPT value.
The resistance to localized corrosion is often assessed by use
of the PREN number (%Cr + 3.3 x %Mo + 16 x %N). Incoloy 925 is made to a minimum PREN
of 40, ensuring a guaranteed and high resistance to pitting and crevice corrosion.
Incoloy 925 has been in service in seawater since 1986 as castings, and since 1989 as
wrought pipes and fittings giving satisfactory performance.
At sea water
temperatures above ambient, 68°F (20°C), the risk of crevice corrosion increases.
Incoloy 925 resists crevice corrosion up to 131°F (55°C) but is limited by the pitting
resistance of the welds to about 104°F (40°C). With the application of post weld
surface treatments, seawater temperatures up to 149°F (65°C) have been handled
successfully.
Short term elevated temperatures upsets are not uncommon in
cooling water circuits. Laboratory tests and field experience have shown that Incoloy
925 does not suffer crevice corrosion easily during short upsets and, when corrosion
does initiate, repassivation occurs readily on cooling, and at temperatures higher than
the normal operating temperature of 104°F (40°C). Super austenitic steels and super
duplex steels that do not contain copper and tungsten have lower repassivation
temperatures than normal operating temperatures, so any corrosion that is initiated
during the upset will continue to propagate when the system reaches normal operating
conditions once more.
Incoloy 925 has excellent resistance to stress corrosion
cracking (SCC) in both chloride environments, and process environments containing
H2S and CO2. Incoloy 925 is listed in ISO 15156 / NACE MR0175
part 3 as being suitable in sour service at 0.2 bar partial pressure of H2S.
In brines with lower chloride contents Incoloy 925 can tolerate much higher pressures
of H2S, as shown in Figure 4. As the pH, at temperature and pressure, increases, so
does the resistance to sulfide SCC (Figure 4).
Figure 4 - Limits of use for Incoloy 925 in brines containing H2S
In common with all high strength steels, duplex and super duplex
stainless steels can be susceptible to hydrogen embrittlement if stressed above the
specified minimum yield strength in the presence of hydrogen. Hydrogen embrittlement
therefore becomes an area for consideration when these steels are used subsea with
conventional cathodic protection. However, the proper application of normal design
stress criteria and coating technology has allowed many subsea projects to utilize
duplex and super duplex stainless steels successfully for a number of years.
Incoloy 925 should be solution annealed in the temperature range
2012-2084°F (1100-1140°C) followed by water quenching.
Hot forming of Incoloy 925 should be carried out in the
temperature range 2012 - 2336°F (1100°C - 1280°C). It is recommended that this is
followed by solution annealing and water quenching. Components should subsequently be
pickled or fully machined.
Incoloy 925 can be adequately cold formed by various processes
but the high mechanical properties should be taken into account. It is recommended that
any cold work in excess of 10% -15% is removed by solution annealing and water
quenching.
It should be noted that cold working above these limits can result in hardness levels
above those specified in standards such as ISO 15156 / NACE MR0175 for cold worked
superduplex.
Where a solution anneal and quench as a post-weld heat treatment
is to be carried out, Incoloy 925 is usually welded with matching composition
consumables (Zeron 100M). With overalloyed consumables (Zeron 100X), no post-weld heat
treatment is necessary. Corrosion and mechanical properties similar to the parent metal
can be obtained following recommended procedures. A separate brochure on the optimum
parameters for a range of welding operations is available from our Sales Department as
bulletin number 105.
Incoloy 925 requires a little more care in machining than the
300 series austenitics. If heavy or uneven machining to tight tolerances is to be
carried out on wrought Incoloy 925 components, machining should be carried out in
stages. As a last resort, a stress relieving heat treatment can be applied but this can
result in a reduction of toughness and corrosion resistance.
ASTM A923 - Test Method A - Sodium Hydroxide
Etch Test for Classification of Etch Structures of Duplex Stainless Steels
ASTM E562 - Standard Test Method for Determining Volume Fraction by
Systematic Manual Point Count
ASTM G48 - Test Method A - Standard Test Methods for Pitting and
Crevice Corrosion Resistance of Stainless Steels
ASTM A923 - Test Method C - Ferric Chloride Corrosion Test for
Classification of Structures of Duplex Stainless Steels
Incoloy 925 Product Range
Surface Treatments
- Xylan 1070 / 1014 / 1400 / 1424
- Xylar 2 / 101
- SermaGard 1105 / 1280
- Dacromet 320 / 500
- TakeCoat 1000 Ceramic
- Magnigard
- MolyKote
Certifications
- ISO 9001 - 2015 Certified
- PED 2014/68/EC
- NACE MR0175/ISO 15156-2
- NORSOK M-650 MDS 055
- DFAR
- MERKBLATT AD 2000 W2/W7/W10